Ceramic fiber is a fibrous lightweight refractory material, mainly composed
of aluminum silicate. It can be divided into two categories based on its mineral
composition: glassy fiber and polycrystalline fiber. Glass fiber is an amorphous
solid fiber formed by the cooling of a molten liquid state; Polycrystalline
fibers are mostly formed by colloidal injection method (or spinning method) and
calcined at high temperatures.
Refractory materials
Ceramic fibers are widely used as insulation and high-temperature resistant
materials in various types of thermal kilns. Due to their significantly lower
capacity than other refractory materials, their heat storage is very small and
their insulation effect is obvious. As lining materials, they can greatly reduce
energy consumption in thermal kilns, bringing a revolution in energy
conservation for thermal kilns. On the other hand, its application technology
and methods have also brought about a revolution in the masonry of thermal
kilns.
1. Current usage status
Ceramic fibers first appeared in 1941, when Bab Wilcox Company in the
United States used natural kaolin to melt and blow into fibers in an electric
arc furnace. In the late 1940s, two American companies produced a series of
aluminum silicate fibers and first applied them in the aviation industry; In the
1960s, the United States developed various ceramic fiber products and used them
for industrial kiln wall lining. In the 1970s, ceramic fibers began to be
produced and used in China, and their application technology was rapidly
promoted in the 1980s. However, the main temperature range used was below 1000
℃, and the application technology was relatively simple and backward. After
entering the 1990s, with the promotion and application of zirconium containing
fibers and polycrystalline alumina fibers, the usage temperature increased to
1000 ℃~1400 ℃. However, due to product quality defects and outdated application
technology, the application fields and methods were limited. For example,
polycrystalline alumina fibers cannot be made into fiber blankets, and product
specifications mainly focus on loose cotton and fiber blocks. Although the
insulation temperature of household appliances has increased, the strength is
poor, limiting the scope of use and shortening the service life.
Zirconium containing fiber is a widely used and low-cost aluminum silicate
fiber produced by the melting method, which can be widely used as a hot surface
full fiber lining for various thermal kilns. Currently, the quality and
application development of domestic products in this area are relatively
backward. Chromium containing fibers have emerged abroad, with higher usage
temperatures than zirconium containing fibers, and there is no report on this in
China.
2. Type and purpose
The main varieties of ceramic fibers include: ordinary aluminum silicate
fibers, high alumina aluminum silicate fibers, aluminum silicate fibers
(containing Cr2O3, ZrO2 or B2O3), polycrystalline alumina fibers, and
polycrystalline mullite fibers. In recent years, some new ceramic fiber
varieties have been successfully developed (or are currently being developed)
abroad, such as magnesium olivine fibers, ceramic fibers (SiO2 CaO MgO series
and Al2O3 CaO series), etc. The main forms of ceramic fiber products include:
ceramic fiber cotton, felt, blanket, module, paper, cloth, belt, rope, etc.
Ceramic fiber blanket (fiber module): It is often made of spun long fibers
using self melting, continuous melting, and continuous casting production
processes. The fibers are interwoven by double-sided needling, and can be
directly used as a flame hot surface. It integrates fire resistance, insulation,
and insulation, and can be used in neutral, oxidizing, and partial reducing
atmospheres for a long time, still maintaining good strength and toughness. The
fiber module made of this fiber blanket does not contain binders and has good
thermal stability. It is widely used in insulation and heat resistance fields
such as petrochemical, metallurgy, and power.
Ceramic fiber board: made of ceramic fibers, binders, and additives through
processes such as pulping, molding, curing, and drying. Ceramic fiber board has
good flexibility, easy cutting, and high strength. It is a new type of
energy-saving and environmental protection product with low thermal conductivity
and low heat storage. It is widely used as a backing for various heating
equipment walls, roofs, and other parts, and is a heavy refractory material.
Ceramic fiber cloth and tape: mainly used for fire doors, industrial kiln
insulation, and insulation of high-temperature pipelines and containers.
Ceramic fiber rope: mainly used for expansion joints in various industrial
kilns, winding insulation of high-temperature pipelines, and insulation of steel
structure connections.